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Polychar are annual conferences originally focused on polymer characterization (hence the acronym Polychar). In the last years, topics have been widely enlarged, including all the topics related to advanced materials. Areas of Polychar 27 cover Synthesis and molecular characterization; Composites and interfaces; Polymer engineering; Nanomaterials and nanotechnology; Smart and functional materials; Sustainability and recycling; Materials for medicine and health; Materials for optics and electronics; Materials for energy and environment; Predictive methods and modeling; Surfaces, adhesion and tribology; Advanced characterization techniques.