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The main goal of this workshop is to establish the current state of art in our understanding of the Physics of Black Hole sources, their spectral and timing signatures and to formulate the key fundamental problems of BH Physics and General Relativity, which can be addressed by future X-ray spectroscopic, timing and polarimetry missions. Topics of the Workshop: 1) Spectra and variability of black-hole binaries 2) Towards the measurement of fundamental parameters 3) Spectral features, hard tails and annihilation lines 4) Expectations from X-ray polarimetric observations of BH candidates.