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Diphenyloxide (DPO) derivatives are important products for modern industry, science and technology. On their base polymers with unique mechanical and optical properties are being developed. AlkylDPO with different functional groups have abilities of substance selforganization and liquid crystals properties, also they able to control plant pathogenic fungi. In spite of useful properties variety of DPO derivatives there are lack of thermodynamic data and fundamental physicochemical properties for them. Up to date references contain data only for diphenyloxide and some nitro-derivatives.