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ИСТИНА ЦЭМИ РАН |
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In this study, we report a simple and quite straightforward supramolecular approach toward novel hybrid cluster-porphyrin (CPn) systems based on 5,15-bis[(p-tolyl)porpyrinato(2-)]zinc as organic part and an octahedral pyridine end-decorated molybdenum(II) halide cluster (Bu4N)2[{Mo6I8}(PyCOO)6], possessing remarkable photophysical properties, as inorganic part.