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ИСТИНА |
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ИСТИНА ЦЭМИ РАН |
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The synthetic approach toward heteronuclear trisphthalocyaninates, containing paramagnetic atoms, includes using of La(Pc)2 as an efficient and convenient source of Pc2- dianions. Indeed, the reaction between double-decker of one metal and La(Pc)2 in the presence of acetilacetonate of another metal under reflux in 1-chloronaphtalene, afforded the heteronuclear complexes. Remarkably, the reaction rate is exceptionally high; only 15 min are required for complete conversion of starting double-decker into the target heteronuclear compound.
№ | Имя | Описание | Имя файла | Размер | Добавлен |
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1. | Полный текст | текст, isbn, обложка сборника | eicc_Polovkova.pdf | 1,3 МБ | 6 февраля 2020 [PolovkovaMarina] |