ИСТИНА

In this work, we report on a new method to synthesize new sponge-like photocatalytic materials comprising graphene oxide (GO) and zinc porphyrin complexes ordered into surface-attached metal-organic frameworks (SURMOFs). To obtain the SURMOF/GO hybrids in a powdered form, we developed a one-pot synthesis of these materials in the GO-stabilized oil-in-water Pickering emulsions. The results of experimental studies involving X‐ray diffraction, UV-vis spectroscopy, BET nitrogen absorption, gas chromatography-mass-spectrometry, and MALDI-TOF spectroscopy. The data suggest that these mesoporous SURMOF/GO hybrids can exploit two different mechanisms yielding different products of photocatalytic degradation of model organic compounds such as rhodamine 6G (Rh6G) and 1,5- dihydroxynaphtalene (DHN).