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The last time the significant research attention is paid to the compounds containing element – element (E = Si, Ge, Sn) bonds. The σ-conjunction is appeared in these derivatives that results in new properties such as conductivity, optic absorbance, luminescence etc. So the investigation of effect of various substituents in oligogermanes on the properties is an actual problem. Here we wish to report on the synthesis, physical properties and reactivity of new germanes, oligogermanes with Si containing groups and related compounds. SL-47; book of abstracts, p.167.