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In this study original membrane catalytic systems active in processes of conversion of methane and biomass products into syngas and hydrogen at moderate temperatures (600-650°C) are presented. It was shown that in dry methane reforming the most active catalysts from the list of studied samples are La-Ce and Pd-Mn on Ni-Al membrane. In steam reforming of ethanol, acetic acid and glycerin membrane catalytic systems, modified by Pd, Pd-Zn and Pd-Co catalysts, shown complete conversions of substrates with high hydrogen selictivity.