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The report presents the study of the unique properties of non-conjugated transparent polymers from the class of aromatic polyether - polyarylene ether ketones, - to form low resistance electrical contact metal/polymer/transparent conductive oxide (TCO). The conductivity mechanisms in thin polymer films in the heterostructure metal/polymer/TCO have been investigated experimentally. Particular attention has been paid to the electronic structure of polymers and mechanisms of a highly conductive state (HCS) formation.