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NEW SUPRAMOLECULAR METALLOGELS DERIVESD FROM ORTHO-PALLADATED BENZYLAMINE AND EXO-DENTATE DIIMINESстатья
- Авторы: Медведько А.В., Вацадзе С.З.
- Журнал: New Materials, Compounds and Applications
- Том: 2
- Номер: 2
- Год издания: 2018
- Первая страница: 103
- Последняя страница: 110
- Аннотация: This Communication describes the serendipitous discovery of the new class of supramolecular metallogels. The target materials were obtained during the attempts to synthesize the binuclear palladium complexes by the reaction of ortho-palladated N,N-dimethylbenzylamine with exo-dentate N-donor ligands – 4,4’-bipyridyl and (E,E)-1,2-bis(4-pyridyl)ethylene – in benzene. Gel drying was made by simple solvent evaporation and by supercritical CO2 drying. The morphology of corresponding xerogels and aerogels as revealed by SEM study showed that the methods of solvent removal is crucial for the solid-state structure of the final materials. The tentative scheme of the gel formation is suggested.
- Добавил в систему: Вацадзе Сергей Зурабович
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | Medvedko_Vatsadze_New_Mat_Comp_Appl_2018.pdf | 748,2 КБ | 30 декабря 2021 [szv] |