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Electrochemical activation of nucleophilic substitution in aryl and vinyl halides with [CpFe(CO)(2)](-) anion using homogeneous redox-catalysisстатья
Информация о цитировании статьи получена из
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Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Magdesieva T.V., Kukhareva I.I., Shaposhnikova E.N., Artamkina G.A., Beletskaya I.P., Butin K.P.
- Журнал: Journal of Organometallic Chemistry
- Том: 526
- Номер: 1
- Год издания: 1996
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 51
- Последняя страница: 58
- DOI: 10.1016/S0022-328X(96)06540-0
- Аннотация: The feasibility of indirect electrochemical activation of nucleophilic substitution in several non-active aryl and vinyl halides with [CpFe(CO)(2)](-) by means of a specially introduced mediator (a reversible redox couple A/A(.-)) has been demonstrated. The efficiency of different mediators for several aryl and vinyl halides as well as the corresponding sigma-aryl and sigma-vinyl derivatives of (eta(5)-cyclopentadienyl)irondicarbonyl has been examined. It was shown that by carefully selecting the mediator it becomes possible to perform the electrochemically induced substitution reaction even in those cases where the substitution products are reduced irreversibly and at less cathodic potentials than the initial substrates.
- Добавил в систему: Магдесиева Татьяна Владимировна