Investigation of the electrochemical behavior of some R-Fe(CO)(2)Cp metallocomplexes containing a sigma-bonded eta(5)-cyclopentadienylirondicarbonyl fragment attached to an sp(2)-hybridized carbon atomстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:Electrochemical oxidation and reduction of a large number of Cp(CO)(2)Fe-R compounds (R = aryl, vinyl, aroyl) with a Fe-C(sp(2)) sigma-bond have been studied at a platinum electrode using cyclic voltammetry and rotating disk-ring electrode techniques. The mechanisms of both oxidation and reduction cannot be rationalized in terms of unified schemes and depend on the nature of the organic fragment R.