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ELECTROCHEMICAL STUDY OF SOME BROMO-SUBSTITUTED [2.2]PARACYCLOPHANESстатья
Информация о цитировании статьи получена из
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Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: BUTIN KP, MOISEEVA AA, MAGDESIEVA TV, SERGEEVA EV, ROZENBERG VI, KHARITONOV VG
- Журнал: Russian Chemical Bulletin
- Том: 43
- Номер: 5
- Год издания: 1994
- Издательство: Springer Nature
- Местоположение издательства: Switzerland
- Первая страница: 783
- Последняя страница: 789
- DOI: 10.1007/BF00717338
- Аннотация: The potentials of electrochemical oxidation (E(1/2)(Ox)) and reduction (E(1/2)(Red)) of monobromo- and isomeric di- and tribromo[2.2]paracyclophanes as well as E(1/2)(Ox) of mono-, di-, and tribromobenzenes were measured in acetonitrile. The similarity between the properties of pseudo-para-disubstituted cyclophanes and meta-disubstituted benzenes, on the one hand, and pseudo-meta-disubstituted cyclophanes and para-disubstituted benzenes, on the other hand, was confirmed by the existence of a linear relationship between E(1/2)(Red) of bromo-substituted [2.2]paracyclophanes and E(1/2)(Red) of the corresponding bromo-substituted benzenes. The results were explained in terms of the qualitative theory of molecular orbitals, taking into account a ''through space'' interaction between the pi-systems of the benzene rings.
- Добавил в систему: Магдесиева Татьяна Владимировна