Decationation of MFI Zeolite with the Use of Direct-Current Electric Field

Budnyak, A.D.; Bedenko, S.P.; Talyshinskii, R.M.; Tret'yakov, V.F.; Ilolov, A.M.

Информация о цитировании статьи получена из Web of Science, Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 4 сентября 2019 г.

Авторы: Budnyak A.D., Bedenko S.P., Talyshinskii R.M., Tret'yakov V.F., Ilolov A.M.
Журнал: Petroleum Chemistry
Том: 59
Номер: 8
Год издания: 2019
Издательство: Pleiades Publishing, Ltd
Местоположение издательства: Road Town, United Kingdom
Первая страница: 870
Последняя страница: 874
DOI: 10.1134/S0965544119080036
Аннотация: A method is proposed for converting an MFI zeolite from the Na- to the H-form using an electric field in a dc electrodialyzer at low voltages in the range of 3 to 12 V. According to X-ray fluorescence analysis, the degree of exchange is 100%; the sodium content in the zeolite was 0.05 wt % before decationation and became 0.00 wt % after it, with the zeolite crystal lattice and morphology remaining unchanged. The catalytic activity of the zeolite before and after the decationation procedure has been tested in the ethanol reforming reaction. The results showing the side to which the proton directs the ethanol reforming reaction are presented. The catalytic testing of the decationated zeolite has shown that the yield of liquid organic products increased to 19.0%, with the proportion of aromatic products being 72.0%.
Добавил в систему: Беденко Станислав Павлович

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