Poly(schiff's bases)-bifluorophores: Synthesis, photophysical properties, non-radiational transfer of energy of electronic excitationстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация: For the first time poly(schiffs bases)-fluorophores with self-fluorescense were synthesised by polycondensation of dialdehydes of dicarboxylic acids and diamines-fluorophores. It was shown that the solutions of these polymers have abnormally high for polymer solutions quantum yield of fluorescence reaching 80% at 20degreesC. High quantum yield of fluorescence is the result of high rigidity of polymer chain. Poly(schiff's bases)-bifluorophores were synthesised and it was shown that in these polymers non-radiative transfer of energy of electron excitation takes place with coefficient or energy transfer reaching 84%.