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Electrochemical hydrogenation of substituted α-phenylvinylphosphonic acids: General characteristics of the reaction layer and prediction of preparative electrolysis conditionsстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Safonova T.Y., Gulyukina N.S., Novakovskaya Y.V., Astaf'ev E.A., Bondarenko G.N., Petrii O.A., Tsirlina G.A., Beletskaya I.P.
- Журнал: Russian Journal of Electrochemistry
- Том: 38
- Номер: 5
- Год издания: 2002
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 457
- Последняя страница: 466
- DOI: 10.1023/A:1015436724272
- Аннотация: The conditions for electrochemical hydrogenation and anodic oxidation of alpha-phenylvinylphosphonic acid and its 4-chloro- and 4-methyl-substituted derivatives on palladized platinum electrodes in aqueous sulfuric-acid solutions are found. It is shown that, in the system under study, the products of strong chemisorption are not the intermediates of the electrocatalytic hydrogenation. The reactant molecules are modeled by quantum-chemical methods in terms of the restricted Hartree-Fock approximation. The calculated charge distributions in reactant molecules are used for estimating the electrostatic components of works of approach and the orientation distributions in the reaction layer.
- Добавил в систему: Петрий Олег Александрович