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Organoelement Compounds Crystallized In Situ: Weak Intermolecular Interactions and Lattice Energiesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 марта 2020 г.
- Авторы: Volodin Alexander D., Korlyukov Alexander A., Smol’yakov Alexander F.
- Журнал: Crystals
- Том: 10
- Номер: 1
- Год издания: 2019
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Первая страница: 15
- DOI: 10.3390/cryst10010015
- Аннотация: The in situ crystallization is the most suitable way to obtain a crystal of a low-melting-point compound to determine its structure via X-Ray diffraction. Herein, the intermolecular interactions and some crystal properties of low-melting-point organoelement compounds (lattice energies, melting points, etc.) are discussed. The discussed structures were divided into two groups: organoelement compounds of groups 13–16 and organofluorine compounds with other halogen atoms (Cl, Br, I). The most of intermolecular interactions in the first group are represented by weak hydrogen bonds and H...H interactions. The crystal packing of the second group of compounds is stabilized by various interactions between halogen atoms in conjunction with hydrogen bonding and stacking interactions. The data on intermolecular interactions from the analysis of crystal packing allowed us to obtain correlations between lattice energies and Hirshfeld molecular surface areas, molecular volumes, and melting points.
- Добавил в систему: Володин Александр Дмитриевич
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 2. | Полный текст | Volodin_i_dr._-_2020_-_Organoelement_Compounds_Crystallized… | 4,6 МБ | 7 февраля 2020 [Robot2100] |