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Characterization and catalytic properties of nanosized cobaltate particles prepared by in situ synthesis inside mesoporous malecular sievesстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Makshina E.A., Sirotin S.V., van_den_Berg M.W.E, Klementiev K.V., Yushchenko V.V., Mazo G.N., Grunert W., Romanovsky B.V.
- Журнал: Applied Catalysis A: General
- Том: 312
- Год издания: 2006
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 59
- Последняя страница: 66
- DOI: 10.1016/j.apcata.2006.06.021
- Аннотация: Bulk lanthanum cobaltate (LaCoO3) with perovskite-like structure and LaCoOx supported onto the mesoporous MCM-41 molecular sieve were synthesized by the conventional citrate method. The prepared samples were characterized by XRD, nitrogen BET measurements, H2-temperature-programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS), XAFS and SEM-energy-dispersive X-ray (EDX) techniques. The turnover frequency of the supported cobaltate in methanol oxidation is two orders of magnitude larger than that of the bulk perovskite material. Based on the characterization results, it is concluded that the supported cobaltate does not form species of LaCoO3 short-range order in MCM-41. The high activity is related to a highly disordered, oxygen-deficient Co oxide phase, which is probably stabilized by the La ions present.
- Добавил в систему: Мазо Галина Николаевна