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Laser diagnostics of self-organization of amphiphiles in aqueous solutions on the example of sodium octanoateстатья Исследовательская статья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 2 декабря 2020 г.
- Авторы: Plastinin Ivan V., Burikov Sergey A., Dolenko Tatiana A.
- Журнал: Journal of Molecular Liquids
- Том: 317
- Год издания: 2020
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 1
- Последняя страница: 12
- Номер статьи: 113958
- DOI: 10.1016/j.molliq.2020.113958
- Аннотация: In this study, a method of non-contact laser diagnostics of self-organization processes of surfactants in aqueous solutions is proposed. The study of solutions of sodium octanoate using laser Raman and near-IR spectroscopy has shown that spectral bands of stretching vibrations of CC-, CH- and OH-groups (including second overtone of the OH-vibrations) of the surfactant molecules and water, as well as bands of intermolecular vibrations of hydrogen bonds O-H⋯O are sensitive to the change the conformation of the hydrocarbon radical of the surfactant and the dynamics of hydrogen bonds during self-organization of surfactants in solution. It was found that the dependence of the spectral characteristics of these bands on concentration of surfactants has peculiarities in the region of critical premicelle concentration (CPMC), first critical micelle concentration (CMC1) and second critical micelle concentration (CMC2). A method of determining the critical concentrations of surfactants in water based on the revealed peculiarities is proposed. A comparative analysis of the obtained CMC values using laser Raman and IR spectroscopy and those measured by independent contact methods – pH-metry, conductivity, surface tension measurement – has shown a good match of the determined parameters. Advantages of the method of laser diagnostics of surfactant self-organization in water were discussed.
- Добавил в систему: Пластинин Иван Владимирович
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