Polytypism of Compounds with the General Formula Cs{Al2[TP6O20]} (T = B, Al): OD (Order-Disorder) Description, Topological Features, and DFT-Calculations

Aksenov, S.M.; Kuznetsov, A.N.; Antonov, A.A.; Yamnova, N.A.; Krivovichev, S.V.; Merlino, S.

Авторы: Aksenov S.M., Kuznetsov A.N., Antonov A.A., Yamnova N.A., Krivovichev S.V., Merlino S.
Журнал: Minerals
Том: 11
Номер: 7
Год издания: 2021
Номер статьи: 708
DOI: 10.3390/min11070708
Аннотация: The crystal structures of compounds with the general formula Cs{[6]Al2[[4]TP6O20]} (where T = Al, B) display order−disorder (OD) character and can be described using the same OD groupoid family. Their structures are built up by two kinds of nonpolar layers, with the layer symmetries Pc(n)2 (L2n+1-type) and Pc(a)m (L2n-type) (category IV). Layers of both types (L2n and L2n+1) alternate along the b direction and have common translation vectors a and c (a ~ 10.0 Å, c ~ 12.0 Å). All ordered polytypes as well as disordered structures can be obtained using the following partial symmetry operators that may be active in the L2n type layer: the 21 screw axis parallel to c [– – 21] or inversion centers and the 21 screw axis parallel to a [21 – –]. Different sequences of operators active in the L2n type layer ([– – 21] screw axes or inversion centers and [21 – –] screw axes) define the formation of multilayered structures with the increased b parameter, which are considered as non-MDO polytypes. The microporous heteropolyhedral MT-frameworks are suitable for the migration of small cations such as Li+, Na+ Ag+. Compounds with the general formula Rb{[6]M3+[[4]T3+P6O20]} (M = Al, Ga; T = Al, Ga) are based on heteropolyhedral MT-frameworks with the same stoichiometry as in Cs{[6]Al2[[4]TP6O20]} (where T = Al, B). It was found that all the frameworks have common natural tilings, which indicate the close relationships of the two families of compounds. The conclusions are supported by the DFT calculation data.
Добавил в систему: Кузнецов Алексей Николаевич

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Polytypism of Compounds with the General Formula Cs{Al2[TP6O20]} (T = B, Al): OD (Order-Disorder) Description, Topological Features, and DFT-Calculationsстатья

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