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Lateral 2D-3D Phase Segregation in Fatty Acid/Fatty Amine Monolayers Induced by Langmuir-Blodgett Depositionстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Lomova Elizaveta M., Turygin Dmitry S., Ezhov Alexander A., Arslanov Vladimir V., Kalinina Maria A.
- Журнал: Journal of Physical Chemistry B
- Том: 113
- Номер: 25
- Год издания: 2009
- Издательство: American Chemical Society
- Местоположение издательства: United States
- Первая страница: 8581
- Последняя страница: 8587
- DOI: 10.1021/jp806317c
- Аннотация: We describe the formation of lateral 2D-3D patterns in mixed multilayer LB films of stearic acid (SA) and octadecylamine (ODA) deposited from aqueous subphases at a basic pH. The 3D particles of SA constituting the micrometer-scale linear assemblies in the LB film are assumed to segregate at the three-phase contact line in the course of film deposition. This 2D-3D phase separation of the two-component system presumably originates from the substrate-induced lowering of the collapse point of SA that leads to spontaneous 3D condensation of an acid on a solid support. The morphology of SA/ODA LB patterns is sensitively influenced by the deposition speed and surface pressure, while the chemistry of the solid support does not affect the resulting structures. The possible mechanism that controls the specific orthogonal arrangement of the 3D phase of SA in the LB film through wettability oscillations is suggested.
- Добавил в систему: Ежов Александр Анатольевич