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The Rate Constant of Electron Impact Dissociation of Carbon Dioxide (Analytical Review of Calculation Methods and Known Results)статья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 22 декабря 2021 г.
- Авторы: Lebedev Yu A., Shakhatov V.A.
- Журнал: High Energy Chemistry
- Том: 55
- Номер: 6
- Год издания: 2021
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 419
- Последняя страница: 435
- DOI: 10.1134/S0018143921300019
- Аннотация: An analytical review has been made of calculation methods and available results of studies on the energy spectrum of electrons in gas discharges in neat carbon dioxide and CO2-containing mixtures. On the basis of a detailed analysis and generalization of calculation results obtained using various models for determining the electron energy spectrum, the rate constant of electron impact dissociation of CO2 in atmospheric-pressure direct-current gas discharge has been found. The range of the reduced electric field (from 55 to 100 Td) in which the predominant mechanism of CO2 decomposition is electron collisions with CO2 molecules has been established. An expression has been obtained for calculating the rate constant of electron impact dissociation of CO2 depending on the reduced electric field. It has been shown that despite the same method of forming a self-consistent set of cross sections, identical values of adjustable parameters can be obtained for different sets of cross sections. This leads to the ambiguity of calculated values for the rate constants of electron impact-induced processes.
- Добавил в систему: Шахатов Вячеслав Анатольевич
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | HEC419.pdf | 1,5 МБ | 11 ноября 2021 [shakhatov@ips.ac.ru] |