Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligandsстатьяИсследовательская статья
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Дата последнего поиска статьи во внешних источниках: 26 января 2022 г.
Аннотация:New SNS-ligands were obtained by consequent ring-opening of substituted thiiranes by lithiated 2,6-lutidine, mono- functionalized SN-ligands having been isolated as the intermediate compounds. The molecular structure of ligand 2,6-Py(CH2CH2CBn2SH)2 was elucidated by XRD analysis.The reaction of AlMe3 with SNS-ligands afforded monomeric methyl aluminum complexes which have been tested in ring- opening polymerization of ε caprolactone in bulk.