Аннотация:A new luminescent hybrid material based on inorganic aerogel "LightSil" (hereinafter referred to as HM-LS) has been fabricated. Organic phosphor has been directly synthesized from boron and 8-hydroxyquinolinol within the aerogel porous structure during its supercritical drying. Intercalation of various amounts of boron ions (0.01, 0.05 and 0.1 wt%) proceed at the gel aging stage. Synthesis and supercritical drying of materials were conducted in high pressure apparatus in a supercritical carbon dioxide medium at 120 bar pressure, 40°C and 500 g/h gas flow rate. The influence of ion amount on the luminescent, physical and structural characteristics of HM-LS were investigated. Analysis of the PL spectra showed that HM-LS with a boron ion concentration of 0.05 wt% has a highest photoluminescence intensity at a wavelength of 513 nm.
