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Decachloro- closo -decaborate anion in copper(II) complexation reactions with N-donor ligands: 35 Cl NQR and X-ray studiesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 13 июня 2017 г.
- Авторы: Avdeeva V.V., Kravchenko E.A., Gippius A.A., Vologzhanina A.V., Malinina E.A., Zhurenko S.V., Buzanov G.A., Kuznetsov N.T.
- Журнал: Polyhedron
- Том: 127
- Год издания: 2017
- Издательство: Pergamon Press
- Местоположение издательства: United States
- Первая страница: 238
- Последняя страница: 247
- DOI: 10.1016/j.poly.2017.02.015
- Аннотация: Copper(II) complexation reactions with neutral N-donor ligands (Bipy, Phen, NH3) in the presence of the bulky decachloro-closo-decaborate dianion were studied. Copper(II) complexes can be prepared from copper(II) salts or copper(I) salts by redox reactions proceeding in air. The complexes [Cu(Bipy)3][B10Cl10]·2CH3CN (1·2CH3CN), [Cu(Bipy)3][B10Cl10]·2Bipy (1·2Bipy), [Cu(Bipy)2Cl]2[B10Cl10]·2DMF (2·2DMF), [Cu(Phen)2Cl]2[B10Cl10]·DMSO·1.25H2O (3·DMSO·1.25H2O) and [Cu(NH3)4(CH3CN)2][B10Cl10] (4) were prepared and characterized by X-ray diffraction as well as IR and 11B NMR spectroscopies. Complexes 1·2CH3CN, 2·2DMF, and 4 were also studied using 35Cl NQR spectroscopy. Secondary interactions were selected from all the interatomic contacts found in these crystals by X-ray diffraction. Hydrogen N–H⋯Cl–B, C–H⋯Cl–B and p⋯π (B–Cl⋯C) secondary bonds were identified in all the compounds, the spectroscopic data being generally in accordance with the results of the X-ray diffraction.
- Добавил в систему: Гиппиус Андрей Андреевич
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| 2. | Акт экспертизы | blank_1.jpg | 304,3 КБ | 22 сентября 2019 [Medvedev_MG] |