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Studies of Multicenter and Intermolecular Dihydrogen B-H···H-C Bonding in [4,8,8′- exo -PPh 3 Cu-4,8,8′-(μ-H) 3 - commo -3,3′-Co(1,2-C 2 B 9 H 9 )(1′,2′-C 2 B 9 H 10 )]статья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 марта 2017 г.
- Авторы: Smol’yakov Alexander F., Korlyukov Alexander A., Dolgushin Fedor M., Balagurova Elena V., Chizhevsky Igor T., Vologzhanina Anna V.
- Журнал: European Journal of Inorganic Chemistry
- Том: 2015
- Номер: 36
- Год издания: 2015
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- Первая страница: 5847
- Последняя страница: 5855
- DOI: 10.1002/ejic.201501029
- Аннотация: An experimentally based and theoretical electron density study of the title compound has been carried out, giving the first experimental description for the two types of bonding: between the transition metal (i.e., Co) and the dicarbollide dianions that occurs through the open C2B3 face of the nido-carborane and between the anionic commo cluster (i.e., Cobdc) and the transition metal (i.e., Cu) involving three unique (B–H)3···Cu bonds. The Co···dicarbollide and Cu···Cobdc bonds are shown to have a multicenter character, whereas direct Co···Cu interaction is found to be absent. The effect of the [Cu(PPH3)]+ association with the Cobdc anion on the Co···dicarbollide bonding is discussed. The description of intramolecular Co···dicarbollide and intermolecular B–H···H–C connectivity in terms of the Hirshfeld approach and Voronoi tessellation is compared with the QTAIM results to confirm their qualitative and semiquantitative similarity.
- Добавил в систему: Вологжанина Анна Владимировна