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Processes in H2PtCl6 ⋅ 6H2O–Solvent Systems. Part I: Alcohol Solutionsстатья
- Авторы: Klimova N.V., Ivanov A.G., Lebedev A.V., Storozhenko P.A.
- Журнал: Doklady Chemistry
- Том: 504
- Номер: 1
- Год издания: 2022
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 88
- Последняя страница: 91
- DOI: 10.1134/s0012500822600122
- Аннотация: Transformation of H2PtCl6 over time under the action of 2-octanol has been studied by NMR, IR spectroscopy, GLC, and GC/MS. It has been found for the first time that the alcohol in a H2PtCl6 ⋅ 6H2O–2-octanol solution is hydrochlorinated to give 2-chlorooctane. Dehydrated platinum chlorides catalyze the elimination of methyl groups in trimethylchlorosilane and hexamethyldisiloxane, which leads to the formation of polydimethylsiloxanes. It has been assumed that the resulting π-complex of H2PtCl4 with octene-1 is not stable in a hydrochloric medium and rapidly decomposes to release chloroalkyl.
- Добавил в систему: Климова Наталия Владимировна