Synthesis of Sandwiched Composite Nanomagnets by Epitaxial Growth of Fe3O4 Layers on SrFe10Cr2O19 Nanoplates in High-Boiling Organic Solvent

Anokhin, E.O.; Deyankov, D.A.; Xia, Z.; Kozlyakova, E.S.; Lebedev, V.A.; Morozov, A.V.; Kozlov, D.A.; Nygaard, R.R.; Petukhov, D.I.; Trusov, L.A.

Авторы: Anokhin Evgeny O., Deyankov Danila A., Xia Zitian, Kozlyakova Ekaterina S., Lebedev Vasily A., Morozov Anatolii V., Kozlov Daniil A., Nygaard Roy R., Petukhov Dmitry I., Trusov Lev A.
Журнал: Nanomaterials
Том: 13
Номер: 1
Год издания: 2023
Издательство: MDPI
Местоположение издательства: Basel, Switzerland
Первая страница: 167
DOI: 10.3390/nano13010167
Аннотация: Herein, we demonstrate the synthesis of sandwiched composite nanomagnets, which consist of hard magnetic Cr-substituted hexaferrite cores and magnetite outer layers. The hexaferrite plate-like nanoparticles, with average dimensions of 36.3 nm × 5.2 nm, were prepared via a glass crystallization method and were covered by spinel-type iron oxide via thermal decomposition of iron acetylacetonate in a hexadecane solution. The hexaferrite nanoplates act as seeds for the epitaxial growth of the magnetite, which results in uniform continuous outer layers on both sides. The thickness of the layers can be adjusted by controlling the concentration of metal ions. In this way, layers with an average thickness of 3.7 and 4.9 nm were obtained. Due to an atomically smooth interface, the magnetic composites demonstrate the exchange coupling effect, acting as single phases during remagnetization. The developed approach can be applied to any spinel-type material with matching lattice parameters and opens the way to expand the performance of hexaferrite nanomagnets due to a combination of various functional properties.
Добавил в систему: Анохин Евгений Олегович

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Synthesis of Sandwiched Composite Nanomagnets by Epitaxial Growth of Fe3O4 Layers on SrFe10Cr2O19 Nanoplates in High-Boiling Organic Solventстатья

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