Level Adiabatic Model for the Dissociation of Diatomic Moleculesстатья
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Дата последнего поиска статьи во внешних источниках: 20 февраля 2024 г.
Аннотация:In strong shock waves in rarefied gases chemical processes occur under conditions of thermodynamicnonequilibrium. Of great interest is the creation of level models of processes to obtaina rate coefficient. The work presents a new level model for dissociation, obtained within the adiabaticapproximation. The model is verified on the basis of available data of quasiclassical trajectory calculations,which analyze the dissociation of N2 molecules in a wide temperature range. Comparison ofthe model with the Treanor–Marrone model and with existing modifications of the Treanor–Marronemodel are discussed.