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Copper(I)-Arsine Clusters with a Near-Unity Phosphorescence Quantum Yield for X-Ray Scintillation and LED Applicationsстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 10 апреля 2024 г.
- Авторы: Demyanov Yan V., Ma Zihao, Jia Zhenglin, Rakhmanova Marianna I., Carignan Gia M., Bagryanskaya Irina Yu, Sulyaeva Veronika S., Globa Anastasiya A., Brel Valery K., Meng Lingqiang, Meng Hong, Lin Qianqian, Li Jing
- Журнал: Advanced Optical Materials
- Год издания: 2024
- Номер статьи: 2302904
- Аннотация: Rare-earth element-free materials that exhibit strong room temperature phosphorescence (RTP) and X-ray scintillation properties are gaining global interest incessantly in the recent years. This work reports a series of easily synthesizable cubane Cu4I4-triarsenic clusters [Cu4I4(R3As)3L] (L = none or nitrile), that exhibit a strong yellow-green RTP with quantum efficiencies up to 100% and short decay times (4.4–4.9 μs). The title cluster complexes display X-ray scintillation properties with a record ultralow detection limit (18.1 nGy s−1) and a perfectly linear dose rate response within a remarkably wide dose rate window (0–640 μGyair s−1). The cluster [Cu4I4(Ph3As)3] is highlighted as an efficient phosphor for UV-pumped white and yellow LED devices, demonstrating an excellent white spectrum with a CIE index of (0.32,0.33) and bright yellow emission, respectively. These results may stimulate the future efforts in designing highly efficient arsenic-based RTP materials and enriching the Cu4I4 cluster family.