Natural polyelectrolyte hydrogels  with two types of cross-links with different energy

Muravlev, D.A.; Doroganov, A.P.; Philippova, O.E.; Shibaev, A.V.

Авторы: Muravlev D.A., Doroganov A.P., Philippova O.E., Shibaev A.V.
Журнал: Eurasian Journal of Chemistry
Том: 29
Номер: 2
Год издания: 2024
Издательство: Karagandy University of the name of academician E.A. Buketov
Местоположение издательства: Kazakhstan
Первая страница: 89
Последняя страница: 95
DOI: 10.31489/2959-0663/2-24-12
Аннотация: For the first time, gels of a polymer cross-linked by two types of ionic cross-links of different energies, namely trivalent chromium (III) ions and divalent iron (II) ions, were prepared. The negatively charged polysaccharide xanthan, a polyelectrolyte of natural origin, was used as a polymer. A study of xanthan gels cross-linked with each cross-linker separately was carried out to identify the optimal concentrations of each cross-linker for the production of a double cross-linked gel. The mechanical properties of hydrogels under oscillatory shear deformations were then studied. It was demonstrated that the simultaneous use of two cross-linkers resulted in a synergistic increase in the elastic modulus (plateau storage modulus) compared to gels cross-linked with each cross-linker separately. For a gel with two types of cross-links, the elastic modulus was 16 Pa. In contrast, for gels cross-linked with either chromium (III) cations or iron (II) cations, the elastic modulus was approximately 0.6 and 0.5 Pa, respectively. The strong effect can be attributed to the different nature of cross-linking between xanthan macromolecules and chromium (III) and iron (II) cations, as well as the different strength of the cross-links formed. The optimal range of pH values was determined in which a synergistic increase in the elastic modulus of gels with two types of cross-links was observed compared to the corresponding gels cross-linked with each cross-linker separately. Consequently, the concurrent utilisation of two cross-linking agents that generate cross-links with disparate energy levels represents an efficacious strategy to improve the tensile strength of polymer hydrogels.
Добавил в систему: Филиппова Ольга Евгеньевна

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