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Molybdenum Catalysts Supported on Porous Aromatic Frameworks in Epoxidation of Olefinsстатья
- Авторы: Makhova V.A., Kulikov L.A., Akopyan A.V., Karakhanov E.A.
- Журнал: Petroleum Chemistry
- Год издания: 2024
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- DOI: 10.1134/s0965544124020208
- Аннотация: A novel catalyst was synthesized by immobilizing a MoO2(acac)2 complex on the surface of a porous aromatic framework functionalized with pyridine-2-carboxaldehyde (PAF-30-NPy). The immobilization was confirmed by IR spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis. The synthesized catalyst was tested in the epoxidation of cyclohexene, cycloheptene, 1-hexene, 1-octene, styrene, and trans-stilbene. The effects of the solvent type and the oxidant content on the olefin conversion were described. The catalyst reusability was further tested, and its activity was evaluated.
- Добавил в систему: Махова Виктория Александровна
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | S0965544124020208.pdf | 999,0 КБ | 21 июня 2024 [Victoria_Yarchak] |