Spectral characteristics and transformations of intermediates in irradiated Freon 11, Freon 113, and Freon 113aстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:Optical absorption bands observable in Freon 11, Freon 113, and Freon 113a irradiated at 77 K were assigned to various intermediates (radical cations, radical ion pairs, and complexes of radicals with ions). The transformations of these species in thermal and photochemical reactions occurring at 77 K were studied. On the basis of experimental results, it was suggested that the radical anions of Freon 11 and Freon 113 are unstable at 77 K and the spatial distribution of the intermediates produced is inhomogeneous.