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Modelling of processes of hydroperoxide epoxidation of olefins. Influence of an olefin on the activity of the decomposition catalyst for ethylbenzene hydroperoxideстатья
Информация о цитировании статьи получена из
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 23 ноября 2017 г.
- Авторы: Akhmedyanova RA, Monayenkov AY, Litvintsev IY, Sapunov VN
- Журнал: Petroleum Chemistry
- Том: 36
- Номер: 1
- Год издания: 1996
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 78
- Последняя страница: 82
- Аннотация: An investigation has been made of the influence of additions of an olefin (Ol) (nonene, cyclohexene) on the kinetics of consumption of ethylbenzene hydroperoxide (EBHP) in the presence of a complex molybdenum-containing catalyst (CMC). It has been shown that, despite the change in the activity of the catalyst in the decomposition reaction under the influence of the epoxidation products, the three routes of EBHP consumption that were found earlier are maintained. The presence of monomeric and oligomeric forms of the catalyst must also be taken into account in the modelling of epoxidation. (C) 1996 Elsevier Science Ltd. All rights reserved.
- Добавил в систему: Сапунов Валентин Николаевич