|
ИСТИНА |
Войти в систему Регистрация |
ИСТИНА ЦЭМИ РАН |
||
Pd-PPy Nanocomposite on the Surface of Carbon Nanotubes: Synthesis and Catalytic Activityстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 10 августа 2018 г.
- Авторы: Gor’kov K.V., Talagaeva N.V., Hierso J.C., Bezverkhyy I.S., Pisareva P.A., Vorotyntsev M., Zolotukhina E.V.
- Журнал: SURFACE INNOVATIONS
- Том: 5
- Номер: 3
- Год издания: 2017
- Первая страница: 121
- Последняя страница: 129
- DOI: 10.1680/jsuin.17.00016
- Аннотация: Nanocomposites Pd-PPy@CNT have been synthesized via one-pot&one-step colloidal synthesis from mixed solution of inorganic salt and pyrrole monomer precursors. This method proposed in our previous papers leads to creation of nanoparticles of the inorganic component distributed inside polymer matrix. Nanocomposites Pd-PPy@CNT have been characterized as heterogeneous catalysts for reactions of direct C-C bond formation. The catalytic activity of the Pd-PPy@CNT nanocomposite was decreasing during repeated catalytic cycles with the same portion of the composite, because of Pd recrystallization inside the conducting polypyrrole matrix. The latter process occurs via specific mechanism of reaction between the solvent and the composite during C-C coupling reaction.
- Добавил в систему: Золотухина Екатерина Викторовна