|
ИСТИНА |
Войти в систему Регистрация |
ИСТИНА ЦЭМИ РАН |
||
MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O-2, and CO2 Storageстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 21 декабря 2017 г.
- Авторы: Alezi Dalal, Belmabkhout Youssef, Suyetin Mikhail, Bhatt Prashant M., Weselinski Lukasz J., Solovyeva Vera, Adil Karim, Spanopoulos Ioannis, Trikalitis Pantelis N., Emwas Abdul-Hamid, Eddaoudi Mohamed
- Журнал: Journal of the American Chemical Society
- Том: 137
- Номер: 41
- Год издания: 2015
- Издательство: American Chemical Society
- Местоположение издательства: United States
- Первая страница: 13308
- Последняя страница: 13318
- DOI: 10.1021/jacs.5b07053
- Аннотация: The molecular building block approach was employed effectively to construct a series of novel isoreticular, highly porous and stable, aluminum-based metal organic frameworks with soc topology. From this platform, three compounds were experimentally isolated and fully characterized: namely, the parent Al-soc-MOF-1 and its naphthalene and anthracene analogues. Al-soc-MOF-1 exhibits outstanding gravimetric methane uptake (total and working capacity). It is shown experimentally, for the first time, that the Al-soc-MOP platform can address the challenging Department of Energy dual target of 0.5 g/g (gravimetric) and 264 cm(3) (STP)/cm(3) (volumetric) methane storage. Furthermore, Al-soc-MOF exhibited the highest total gravimetric and volumetric uptake for carbon dioxide and the utmost total and deliverable uptake for oxygen at relatively high pressures among all microporous MOFs. In order to correlate the MOP pore structure and functionality to the gas storage properties, to better understand the structure property relationship, we performed a molecular simulation study and evaluated the methane storage performance of the Al-soc-MOP platform using diverse organic linkers. It was found that shortening the parent Al-soc-MOP-1 linker resulted in a noticeable enhancement in the working volumetric capacity at specific temperatures and pressures with amply conserved gravimetric uptake/working capacity. In contrast, further expansion of the organic linker (branches and/or core) led to isostructural Al-soc-MOFs with enhanced gravimetric uptake but noticeably lower volumetric capacity. The collective experimental and simulation studies indicated that the parent Al-soc-MOP-1 exhibits the best compromise between the volumetric and gravimetric total and working uptakes under a wide range of pressure and temperature conditions.
- Добавил в систему: Соловьева Вера Александровна