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Heteroleptic naphthalo-phthalocyaninates of lutetium: synthesis and spectral and conductivity propertiesстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 29 мая 2015 г.
- Авторы: Dubinina T.V., Kosov A.D., Petrusevich E.F., Maklakov S.S., Borisova N.E., Tomilova L.G., Zefirov N.S.
- Журнал: Dalton Transactions
- Том: 44
- Год издания: 2015
- Издательство: Royal Society of Chemistry
- Местоположение издательства: United Kingdom
- Первая страница: 7973
- Последняя страница: 7981
- DOI: 10.1039/C5DT00635J
- Аннотация: Novel heteroleptic naphthalo-phthalocyaninates of lutetium possessing a symmetrical substituted naphthalocyanine deck were synthesized on the basis of two preformed synthetic blocks: naphthalocyanine ligand and lutetium phthalocyaninates. The compounds obtained were characterized by 1H NMR and high-resolution MALDI-TOF/TOF mass spectrometry. The correlation between the nature of the substituents and the spectral properties of the target complexes was determined by the introduction of electrondonating (aryl-, aryloxy-) or electron-withdrawing (chloro-) substituents into the phthalocyanine deck. In addition, the nature of peripheral substituents was shown not to affect drastically the phthalocyanine conductivity and activation energy. Conductivity properties depend on thin film morphology which, in turn, relies on intermolecular π–π interactions.
- Добавил в систему: Дубинина Татьяна Валентиновна