CAN catalysis and click chemistry routes in the synthesis of carborane-containing ferrocenes

Ol'shevskaya, V.A.; Makarenkov, A.V.; Borisov, Y.A.; Ananyev, I.V.; Kononova, E.G.; Kalinin, V.N.; Ponomaryov, A.B.

Информация о цитировании статьи получена из Web of Science, Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 20 марта 2018 г.

Авторы: Ol'shevskaya Valentina A., Makarenkov Anton V., Borisov Yury A., Ananyev Ivan V., Kononova Elena G., Kalinin Valery N., Ponomaryov Andrey B.
Журнал: Polyhedron
Том: 141
Год издания: 2018
Издательство: Pergamon Press
Местоположение издательства: United States
Первая страница: 181
Последняя страница: 190
DOI: 10.1016/j.poly.2017.11.034
Аннотация: CAN-catalyzed reactions between a-ferrocenyl ethanol or ferrocenyl methanol and S-, N- and O-carborane nucleophiles are reported. This approach is an efficient and simple procedure for the preparation of carborane derivatives containing ferrocenyl units. Energy and geometry optimizations of some carboranylthio-, carboranylamino- and carboranyloxy-substituted ferrocenes have been calculated using the density functional theory. A series of new ferrocene-containing carborane 1,2,3-triazoles have been synthesized in good yields through a facile copper-mediated 1,3-dipolar cycloaddition reactions of alkynyl ferrocenes with [(o-carboran-1-yl)methyl]azide. Molecular structure of carborane-substituted ferrocenyl triazole was established by single crystal X-ray diffraction study. Representative examples of all ferrocenyl carboranes prepared were characterized by IR, 1H and 11B NMR spectroscopy.
Добавил в систему: Кононова Елена Германовна

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CAN catalysis and click chemistry routes in the synthesis of carborane-containing ferrocenesстатья

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